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ZHANG Yu, LI Yong, WANG Yanbin, WANG Zhuangsen, ZHAO Shihu, HAN Wenlong. SAXS-based nano-scale pore structure characteristics of coals with different metamorphic degrees[J]. COAL GEOLOGY & EXPLORATION, 2021, 49(6): 142-150. DOI: 10.3969/j.issn.1001-1986.2021.06.017
Citation: ZHANG Yu, LI Yong, WANG Yanbin, WANG Zhuangsen, ZHAO Shihu, HAN Wenlong. SAXS-based nano-scale pore structure characteristics of coals with different metamorphic degrees[J]. COAL GEOLOGY & EXPLORATION, 2021, 49(6): 142-150. DOI: 10.3969/j.issn.1001-1986.2021.06.017
shu

SAXS-based nano-scale pore structure characteristics of coals with different metamorphic degrees

  • School of Geoscience and Surveying, China University of Mining and Technology(Beijing), Beijing 100083, China

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  • Received Date: May 24, 2021
  • Revised Date: September 06, 2021
  • Available Online: December 29, 2021
  • Published Date: December 24, 2021
    Graphical Abstract
    • Abstract
  • In order to reveal the characteristics of nano-scale pores in coals with different metamorphic degrees, the small-angle X-ray scattering method (SAXS) is used to obtain the porosity, pore size distribution, specific surface area and fractal dimension of 15 samples whose vitrinite reflectance Rmax is 0.31%-6.24%, and the low temperature CO2 and N2 adsorption DFT model results are used to verify the pore size distribution. The results show: during coalification process, when Rmax is < 0.5%, the porosity and the specific surface area of coal increase with the increase of metamorphic degree, the micropores(< 2 nm) content increases seldomly, the mesoporous(2-50 nm) and microporous(50-100 nm) content increase greatly, and the surface of coal is gradually smooth. When Rmax=0.5%-1.4%, the porosity and the specific surface area decrease, and each type of pore content is reduced, and the surface of coal is gradually smooth. When Rmax=1.4%-4.0%, the porosity and specific surface area of coal rock increase, the microporous content increases, and the mesoporous and microporous content are nearly stable, and the surface of the coal is gradually rough. When Rmax > 4.0%, the porosity and specific surface area of coal increase, the microporous growth is slow, and the surface of coal is gradually smooth.
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