Volume 47 Issue 4
Aug.  2019
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OU Jinping, ZHENG Liugen, WEI Xiangping, Liu Sikui, LI Liyuan, LIU Meng, HUANG Xiaoyu. Occurrence of antimony in magmatic intrusive coal seam: A case study from the Wolonghu coal mine, Huaibei coalfield, China[J]. COAL GEOLOGY & EXPLORATION, 2019, 47(4): 63-68. DOI: 10.3969/j.issn.1001-1986.2019.04.010
Citation: OU Jinping, ZHENG Liugen, WEI Xiangping, Liu Sikui, LI Liyuan, LIU Meng, HUANG Xiaoyu. Occurrence of antimony in magmatic intrusive coal seam: A case study from the Wolonghu coal mine, Huaibei coalfield, China[J]. COAL GEOLOGY & EXPLORATION, 2019, 47(4): 63-68. DOI: 10.3969/j.issn.1001-1986.2019.04.010
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Occurrence of antimony in magmatic intrusive coal seam: A case study from the Wolonghu coal mine, Huaibei coalfield, China

  • 1. Institute of Physical Science and Information Technology, Anhui University, Hefei 230601, China;

  • 2. School of Resources and Environmental Engineering, Anhui University;Anhui Mining Ecological Remediation Engineering Laboratory, Hefei 230601, China;

  • 3. Huaibei Mining(Group) Co., Ltd., Anti-piping and Measuring Department, Huaibei 235000, China

Funds: 

National Natural Science Foundation of China(41373108,41702176)

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  • Received Date: February 21, 2019
  • Published Date: August 24, 2019
    Graphical Abstract
    • Abstract
  • In order to investigate the influence of magmatic alteration on the occurrence characteristics of antimony in coal seam, 12 samples of magmatic magma and coal were collected from Wolonghu coal mine in Huaibei coalfield, Anhui Province, and the content of Sb was determined by atomic fluorescence spectrometry(AFS). The coal quality parameters are analyzed. The results are as follows:the coal in Wolonghu magmatic intrusion area has the characteristics of ultra-low volatile matter, medium ash content and ultra-low sulfur content. And the main forms of sulfur in coal are organic sulfur and pyrite sulfur. Under the influence of magmatic hydrothermal solution, ash in coal seam increases and volatile content decreases. The content of antimony in Wolonghu coal mine is obviously enriched, with an average of 10.48 mg/kg. The average content of Sb in the coal above the intrusive rock is obviously increased, and the content of Sb in the contact zone of coal and rock reaches the highest value(13.93 mg/kg). The antimony in magmatic altered coal mainly exists in the form of inorganic binding(r=0.74), while organic sulfur is negatively correlated with Sb in coal(r=-0.60). The magmatic intrusion resulted in the coal quality characteristics and the occurrence of antimony in Wolonghu coal mine. This result enriches the environmental geochemical study of antimony in coal under special geological process.
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