Organic geochemistry of the Jurassic tar-rich coal in Northern Shaanxi Province
-
摘要: 富油煤的有机地球化学特征对研究其形成时期的古沉积环境和演化过程具有重要意义。以陕北地区侏罗纪延安组6个主采煤层为研究对象，运用煤质分析和气相色谱–质谱联用方法分析其有机地球化学特征。结果表明：陕北地区延安组主采煤的氯仿沥青“A”含量较高，饱芳比较低；正构烷烃呈单峰型分布，中链饱和烃占优势，Pr/nC17、Ph/nC18、Pr/Ph的值较高；C28和C29的规则甾烷和重排甾烷占主导地位。分析表明：陕北地区延安组主采煤层处于低热–成熟阶段，为富氢基质镜质体和壳质组生油的有利阶段；有机质来源以陆生高等植物为主并有部分水生生物混入，形成于贫氧的泥炭沼泽环境，且经历了较强的生物降解作用，为富氢组分的形成提供了有利的条件。Abstract: The organic geochemical characteristics of tar-rich coal are of great significance to study the paleosedimentary environment and evolution of coal seams. Taking coal samples from 6 main coal seams of Yan'an Formation in Northern Shaanxi Province as the research object, this paper analyses the organic geochemical characteristics of coal seams by coal quality analysis and gas chromatography-mass spectrometry. The results showed that coal samples had a high abundance of chloroform asphalt "A" and a low saturated hydrocarbon/aromatic hydrocarbon ratios, characterized by the unimodal pattern of n-alkanes and dominated by medium chainsaturated hydrocarbons. The ratios of Pr/C17, Ph/C18and Pr/Ph were relatively high, regular sterane and diasteranes of C28 and C29 were dominant in steranes. The organic matter was in the low-mature-mature stage, which was a favorable stage for perhydrousvitrinite and lipinite to generate oil. The source of organic matter were from terrestrial organic matte and aquatic organisms and which formed in the anoxic environment and undergoed strong biodegradation. All of these provided favorable conditions for the formation of perhydrousvitrinite.
-
Keywords:
- Northern Shaanxi Province /
- Yan'an Formation /
- tar-rich coal /
- organic geochemistry
-
-
![]()
图 1 鄂尔多斯盆地延安组地层综合柱状图
Fig. 1 Stratigraphic section of the Yan'an Formation in Ordos Basin
![]()
图 3 各煤层中藿烷(m/z=191)的质量色谱图
1—18α(H)22, 29, 30-三降藿烷(Ts)；2—17α(H)22, 29, 30-三降藿烷(Tm)；3—17α(H), 21β(H)-30-降藿烷；4—17β(H), 21α(H)-30-降藿烷；5—17α(H), 21β(H)-藿烷；6—17β(H), 21β(H)-降藿烷；7—17β(H), 21α(H)-藿烷；8—22S-17α(H), 21β(H)-升藿烷；9—22R-17α(H), 21β(H)-升藿烷；10—22(S+R)17β(H), 21α(H)-升藿烷；11—22S-17α(H), 21β(H)-二升藿烷；12—22R-17α(H), 21β(H)-二升藿烷
Fig. 3 Partial m/z=191 mass chromatograms from coal seams
![]()
图 4 各煤层中甾烷(m/z=217)的质量色谱图
1—C28βα20S重排胆甾烷；2—C28βα20R重排胆甾烷；3—C29βα20R重排胆甾烷；4—C29αβ20S重排胆甾烷；5—C28αββ20R胆甾烷；6—C28αββ20S胆甾烷；7—C28ααα20R胆甾烷；8—C29ααα20S胆甾烷；9—C29αββ20R胆甾烷；10—C29αββ20S胆甾烷；11—C29ααα20R胆甾烷
Fig. 4 Partial m/z=217 mass chromatograms from coal seams
表 1 煤层工业分析和饱和有机质成熟度指标
Table 1 Proximate analyses and maturity parameters of organic matter
煤层 工业分析ω/% 成熟度指标 Mad Ad Vdaf Tar, d Rran/% Ts/(Ts+Tm) C31αβ(22S)/(22S+22R) C2920Rαββ/(αββ+ααα) αααC2920S/(20S+20R) 12煤 7.29 10.52 32.51 7.98 0.56 0.56 0.34 0.62 0.33 22煤 9.05 10.46 32.32 8.61 0.52 0.71 0.32 0.59 0.37 31煤 7.95 7.56 34.87 9.01 0.46 0.71 0.37 0.53 0.29 42煤 7.05 7.39 37.40 11.5 0.53 0.79 0.50 0.42 0.49 43煤 6.49 8.12 36.63 10.8 0.51 0.78 0.47 0.44 0.43 52煤 6.31 7.46 37.64 11.3 0.54 0.77 0.52 0.56 0.28 平均值 7.36 8.59 35.23 9.87 0.52 0.72 0.42 0.53 0.36 
下载: 导出CSV
表 2 煤层抽提物含量及饱和烃参数
Table 2 Contents of organic extracts and some parameters derived from saturated hydrocarbon of coal samples
煤层 抽提率/% 族组分ω/% 饱和烃/芳烃 正构烷烃 类异戊二烯烃 饱和烃 芳香烃 非烃+沥青质 碳数范围 主碳峰 CPI C12—C19/% C20—C24/% C25—C31/% Pr/C17 Ph/C18 Pr/Ph 12煤 0.69 14.46 38.25 47.29 0.38 12~30 C23 1.32 31.47 43.1 25.45 1.92 0.49 2.74 22煤 0.81 19.19 48.48 32.32 0.40 15~29 C18 1.42 37.67 40.79 21.52 0.48 0.51 1.62 31煤 0.58 11.84 37.17 50.99 0.32 15~29 C23 1.80 16.23 61.38 22.38 0.65 0.48 2.67 42煤 1.14 18.08 34.18 47.74 0.53 13~30 C25 1.58 13.75 46.66 39.59 0.76 0.47 1.96 43煤 0.51 16.77 38.39 44.84 0.44 15~29 C25 1.80 15.54 54.6 29.86 1.06 0.55 1.58 52煤 0.90 22.90 41.45 35.65 0.55 13~29 Pr 1.52 35.94 45.36 18.68 0.79 0.94 2.02 平均值 0.77 17.21 39.65 43.14 0.44 — — 1.57 25.10 48.65 26.25 0.94 0.57 2.10
下载: 导出CSV
-
[1] 矿产资源工业要求手册编委会. 矿产资源工业要求手册(2014修订版)[M]. 北京: 地质出版社, 2014. Committee for The Preparation of a handbook on industrial requirements for mineral resources. handbook of industrial requirements for mineral resources(2014)[M]. Beijing: Geology Press, 2014.
[2] 马丽, 拓宝生. 陕西富油煤资源量居全国之首榆林可"再造一个大庆油田"[J]. 陕西煤炭, 2020(5): 220. https://www.cnki.com.cn/Article/CJFDTOTAL-SXMJ202001055.htm [3] 张天福, 孙立新, 张云, 等. 鄂尔多斯盆地北缘侏罗纪延安组、直罗组泥岩微量、稀土元素地球化学特征及其古沉积环境意义[J]. 地质学报, 2016, 90(12): 3454-3471. DOI: 10.3969/j.issn.0001-5717.2016.12.013 ZHANG Tianfu, SUN Lixin, ZHANG Yun, et al. Geochemical characteristics of the Jurassic Yan'an and Zhiluo Formations in the northern margin of Ordos Basin and their paleoenvironmental implications[J]. Acta Geologica Sinica, 2016, 90(12): 3454-3471. DOI: 10.3969/j.issn.0001-5717.2016.12.013
[4] 雷开宇, 刘池洋, 张龙, 等. 鄂尔多斯盆地北部侏罗系泥岩地球化学特征: 物源与古沉积环境恢复[J]. 沉积学报, 2017, 35(3): 621-636. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB201703019.htm LEI Kaiyu, LIU Chiyang, ZHANG Long, et al. Element geochemical characteristics of the Jurassic mudstones in the northern Ordos Basin: Implications for tracing sediment sources and paleoenvironment restoration[J]. Acta Sedimentologica Sinica, 2017, 35(3): 621-636. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB201703019.htm
[5] 王东东, 邵龙义, 李智学, 等. 鄂尔多斯盆地延安组层序地层格架与煤层形成[J]. 吉林大学学报(地球科学版), 2013, 43(6): 1726-1739. https://www.cnki.com.cn/Article/CJFDTOTAL-CCDZ201306003.htm WANG Dongdong, SHAO Longyi, LI Zhixue, et al. Sequence stratigraphic framework and coal formation of Yan'an Formation in Ordos Basin[J]. Journal of Jilin University(Earth Science Edition). 2013, 43(6): 1726-1739. https://www.cnki.com.cn/Article/CJFDTOTAL-CCDZ201306003.htm
[6] 庞军刚, 陈全红, 李文厚, 等. 鄂尔多斯盆地延安组标志层特征及形成机理[J]. 西北大学学报(自然科学版), 2012, 42(5): 806-812. DOI: 10.3969/j.issn.1000-274X.2012.05.021 PANG Jungang, CHEN Quanhong, LI Wenhou, et al. The characteristics and forming mechanism of marker bed in Yan'an Formation, Ordos Basin[J]. Journal of Northwest University(Natural Science Edition), 2012, 42(5): 806-812. DOI: 10.3969/j.issn.1000-274X.2012.05.021
[7] 刘东娜, 周安朝, 刘建权. 东胜煤田侏罗系延安组煤中稀土元素地球化学特征[J]. 中国煤田地质, 2007, 19(2): 20-22. DOI: 10.3969/j.issn.1674-1803.2007.02.007 LIU Dongna, ZHOU Anchao, LIU Jianquan. Geochemical characteristics of rare earth elements in Yan'an Formation, Jurassic System, Dongsheng Coalfield[J]. Coal Geology of China, 2007, 19(2): 20-22. DOI: 10.3969/j.issn.1674-1803.2007.02.007
[8] 汪小妹, 焦养泉, 吴立群, 等. 鄂尔多斯盆地东胜-神木地区侏罗系煤中常量元素地球化学特征[J]. 沉积学报, 2011, 29(3): 520-528. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB201103014.htm WANG Xiaomei, JIAO Yangquan, WU Liqun, et al. Major element geochemistry of Jurassic coal in Dongsheng-Shenmu area, Ordos Basin[J]. Acta Sedimentologica Sinica, 2011, 29(3): 520-528. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB201103014.htm
[9] 王华, 张国涛, 白妮. 西北侏罗纪煤中微量元素含量分布特征[J]. 洁净煤技术, 2018, 24(4): 25-33. https://www.cnki.com.cn/Article/CJFDTOTAL-JJMS201804005.htm WANG Hua, ZHANG Guotao, BAI Ni. Distribution characteristics of trace elements in Jurassic coal in Northwest China[J]. Clean Coal Technology, 2018, 24(4): 25-33. https://www.cnki.com.cn/Article/CJFDTOTAL-JJMS201804005.htm
[10] 杜美利, 杨宗义, 郎群, 等. 榆树湾侏罗纪煤中微量有害元素迁移规律研究[J]. 中国煤炭, 2017, 43(3): 140-144. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGME201703032.htm DU Meili, YANG Zongyi, LANG Qun, et al. Study on migration rule of trace hazardous elements in Jurassic coal of Yushuwan[J]. China Coal, 2017, 43(3): 140-144. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGME201703032.htm
[11] 余学海, 孙平, 张军营, 等. 神府煤矿物组合特性及微量元素分布特性定量研究[J]. 煤炭学报, 2015, 40(11): 2683-2689. https://www.cnki.com.cn/Article/CJFDTOTAL-MTXB201511030.htm YU Xuehai, SUN Ping, ZHANG Junying, et al. Quantitative investigations on mineral matter and distributions of trace elements in Shengfu coal[J]. Journal of China Coal Society, 2015, 40(11): 2683-2689. https://www.cnki.com.cn/Article/CJFDTOTAL-MTXB201511030.htm
[12] 麻栋, 白向飞, 丁华, 等. 神东地区侏罗纪煤中矿物的热转化特性[J]. 煤炭转化, 2019, 42(4): 58-65. https://www.cnki.com.cn/Article/CJFDTOTAL-MTZH201904008.htm MA Dong, BAi Xiangfei, DING Hua, et al. Thermal conversion characteristics of minerals in Shendong Jurassic coal[J]. Coal Conversion, 2019, 42(4): 58-65. https://www.cnki.com.cn/Article/CJFDTOTAL-MTZH201904008.htm
[13] 杜美利, 蔡会武, 王水利, 等. 陕北高挥发分烟煤煤质特征与应用研究[J]. 煤田地质与勘探, 2004, 32(5): 10-12. https://www.cnki.com.cn/Article/CJFDTOTAL-MDKT200405003.htm DU Meili, CAI Huiwu, WANG Shuili, et al. Goal property and application of high volatile bituminous coal in the northern Shaanxi Province[J]. Coal Geology & Exploration, 2004, 32(5): 10-12. https://www.cnki.com.cn/Article/CJFDTOTAL-MDKT200405003.htm
[14] 杜芳鹏, 李聪聪, 乔军伟, 等. 陕北府谷矿区煤炭资源清洁利用潜势及方式探讨[J]. 煤田地质与勘探, 2018, 46(3): 11-14. DOI: 10.3969/j.issn.1001-1986.2018.03.003 DU Fangpeng, LI Congcong, QIAO Junwei, et al. Discussion on the potential and way of clean utilization of coal resources in Fugu mining area, northern Shaanxi[J]. Coal Geology & Exploration, 2018, 46(3): 11-14. DOI: 10.3969/j.issn.1001-1986.2018.03.003
[15] 魏云迅, 吴军虎, 杜芳鹏, 等. 鄂尔多斯盆地府谷矿区直接液化用煤潜力分析[J]. 中国煤炭, 2018, 44(3): 46-52. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGME201803010.htm WEI Yunxun, WU Junhu, DU Fangpeng, et al. Potential analysis of coal for direct liquefaction in Fugu mining area of Ordos Basin[J]. China Coal, 2018, 44(3): 46-52. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGME201803010.htm
[16] 秦身钧, 陆青锋, 吴士豪, 等. 重庆中梁山晚二叠世煤有机地球化学特征[J]. 煤炭学报, 2018, 43(7): 1973-1982. https://www.cnki.com.cn/Article/CJFDTOTAL-MTXB201807021.htm QIN Shenjun, LU Qingfeng, WU Shihao, et al. Organic geochemistry of the Late Permian coal from the Zhongliangshan mine, Chongqing[J]. Journal of China Coal Society, 2018, 43(7): 1973-1982. https://www.cnki.com.cn/Article/CJFDTOTAL-MTXB201807021.htm
[17] PETERSEN H I, Sofie Lindström. Synchronous wildfire activity rise and mire deforestation at the Triassic-Jurassic Boundary[J]. Plos One, 2012, 7: 1-15. http://www.ncbi.nlm.nih.gov/pubmed/23077574
[18] 王绍清, 孙翊博, 沙玉明. 不同聚煤区内富氢煤有机地球化学特征研究[J]. 煤炭科学技术, 2018, 46(9): 233-238. https://www.cnki.com.cn/Article/CJFDTOTAL-MTKJ201809036.htm WANG Shaoqing, SUN Yibo, SHA Yuming. Study on organic geochemical features of rich hydrogen coal in different coal accumulation areas[J]. Coal Science and Technology, 2018, 46(9): 233-238. https://www.cnki.com.cn/Article/CJFDTOTAL-MTKJ201809036.htm
[19] 牛永杰, 赵巧静, 李新. 广西合山石村矿超高有机硫煤饱和烃特征分析[J]. 燃料化学学报, 2020, 48(4): 395-404. https://www.cnki.com.cn/Article/CJFDTOTAL-RLHX202004002.htm NIU YongJie, ZHAO QiaoJing, LI Xin. Saturated hydrocarbon characteristics of superhigh-organic-sulfur coals in Heshan Shicun Mine, Guangxi[J]. Journal of Fuel Chemistry and Technology, 2020, 48(4): 395-404. https://www.cnki.com.cn/Article/CJFDTOTAL-RLHX202004002.htm
[20] ROMERO-SARMIENTO M, RIBOULLEAU A, VECOLI M, et al. Aliphatic and aromatic biomarkers from Carboniferous coal deposits at Dunbar(East Lothian, Scotland): Palaeobotanical and palaeoenvironmental significance[J]. Palaeogeography, Palaeo-climatology, Palaeoecology, 2011, 309(3/4): 309-326. http://www.sciencedirect.com/science/article/pii/S0031018211003257
[21] GAN Huajun, WANG Hua, CHEN Jie, et al. Geochemical characteristics of Jurassic coal and its paleoenvironmental implication in the eastern Junggar Basin, China[J]. Journal of Geochemical Exploration, 2018, 188: 73-86. http://www.ingentaconnect.com/content/el/03756742/2018/00000188/00000001/art00007
[22] IZART A, SUAREZ-RUIZ I, BAILEY J. Paleoclimate reconstruction from petrography and biomarker geochemistry from Permian humic coals in Sydney Coal Basin(Australia)[J]. International Journal of Coal Geology, 2015, 138: 145-157. http://www.sciencedirect.com/science/article/pii/S0166516214002729
[23] 刘洪军, 秦黎明, 张枝焕. 准噶尔盆地西北部和什托落盖盆地侏罗系烃源岩芳烃分布特征及地球化学意义[J]. 天然气地球科学, 2012, 23(6): 1104-1115. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201206018.htm LIU Hongjun, QIN Liming, ZHANG Zhihuan. Geochemical significance and distribution characteristics of polycyclic aromatic hydrocarbons from the Jurassic source rocks in the Heshituoluogai Basin, Northwest Junggar[J]. Natural Gas Geoscience, 2012, 23(6): 1104-1115. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201206018.htm
[24] 王双明. 鄂尔多斯盆地聚煤规律及煤炭资源评价[M]. 北京: 煤炭工业出版社, 1996: 84-86. WANG Shuangming. Coal accumulating and coal resource evaluation of Ordos Basin[M]. Beijing: China Coal Industry Publishing House, 1996: 84-86.
[25] 许云. 中国西北地区中侏罗世煤中古野火证据及对古气候的影响[D]. 北京: 中国矿业大学(北京), 2019. XU Yun. Evidences of widespread wild fires in coal seams from the Middle Jurassic of the Northwest China and its impact on paleoclimate[D]. Beijing: China University of Mining & Technology(Beijing), 2019.
[26] 黄第藩, 熊传武. 含煤地层中石油的生成、运移和生油潜力评价[J]. 勘探家, 1996, 1(2): 6-11. https://www.cnki.com.cn/Article/CJFDTOTAL-KTSY199602003.htm HUANG Difan, XIONG Chuanwu. Generaiton migration and evaluation of hydrocarbon generation potential of oil formed in coal-bearing strata[J]. Explorationist, 1996, 1(2): 6-11. https://www.cnki.com.cn/Article/CJFDTOTAL-KTSY199602003.htm
[27] 姚素平, 张景荣, 胡文瑄, 等. 鄂尔多斯盆地中生界煤成烃潜力的实验研究[J]. 煤田地质与勘探, 2004, 32(1): 24-28. https://www.cnki.com.cn/Article/CJFDTOTAL-MDKT200401008.htm YAO Suping, ZHANG Jingrong, HU Wenxuan. Experimental study of hydrocarbon generation potentiality of Mesozoic coal measure, Ordos Basin[J]. Coal Geology & Exploration, 2004, 32(1): 24-28. https://www.cnki.com.cn/Article/CJFDTOTAL-MDKT200401008.htm
[28] STACH E, MACHOWSKY M, TEICHMULLER M, et al. Coal petrology(the third edition)[M]. Berlin: Borntraeger, 1982: 530-545.
[29] 刘光祥, 潘文蕾, 邵海宁. 西北地区中下侏罗统煤成烃源岩评价[J]. 石油实验地质, 2000, 22(3): 232-235. https://www.cnki.com.cn/Article/CJFDTOTAL-SYSD200003007.htm LIU Guangxiang, PAN Wenlei, SHAO Haining. Evaluation of hydrocarbon generating potential of the Middle and Lower Jurassic coal in Northwest China[J]. Experimental Petroleum Geology, 2000, 22(3): 232-235. https://www.cnki.com.cn/Article/CJFDTOTAL-SYSD200003007.htm
[30] 李小彦, 降文萍, 武彩英. 陕北煤田侏罗纪煤直接液化问题探讨[J]. 煤炭科学技术, 2005, 33(4): 59-63. https://www.cnki.com.cn/Article/CJFDTOTAL-MTKJ20050400H.htm LI Xiaoyan, JIANG Wenping, WU Caiying. Discussion on direction liquefaction with Jurassic coal from Shanbei Coal Field[J]. Coal Science and Technology, 2005, 33(4): 59-63. https://www.cnki.com.cn/Article/CJFDTOTAL-MTKJ20050400H.htm
[31] 中国科学院地球化学研究所. 有机地球化学[M]. 北京: 科学出版社, 1982: 70-71. Institute of Geochemistry Chinese Academy Science. Organic geochemistry[M]. Beijing: Science Press, 1982: 70-71.
[32] 王森, 张明震, 李爱静, 等. 潮水盆地和民和盆地中侏罗统青土井组煤系烃源岩有机地球化学特征及其意义[J]. 天然气地球科学, 2020, 31(2): 282-294. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX202002013.htm WANG Sen, ZHANG Mingzhen, LI Aijing, et al. Organic geochemical characteristics of Qingtujing Formation coal-measure source rocks in the Chaoshui Basin and Minhe Basin and their hydrocarbon-generation significances[J]. Natural Gas Geoscience, 2020, 31(2): 282-294. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX202002013.htm
[33] 王崇敬, 张鹤, 李世宇, 等. 基于分子标志物的有机质成熟度评价参数选择及其适用范围分析[J]. 地质科技情报, 2018, 37(4): 202-211. https://www.cnki.com.cn/Article/CJFDTOTAL-DZKQ201804028.htm WANG Chongjing, ZHANG He, LI Shiyu, et al. Maturity parameters selection and applicable range analysis of organic matter based on molecular markers[J]. Geological Science and Technology Information, 2018, 37(4): 202-211. https://www.cnki.com.cn/Article/CJFDTOTAL-DZKQ201804028.htm
[34] 周光甲. 用广义对应分析法筛选生物标志物指标: 论济阳坳陷原油的成熟度[J]. 石油与天然气地质, 1987, 8(2): 153-162. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT198702006.htm ZHOU Guangjia. Screening of biomarker indices by generalized correspondence analysis discussion on crude oil maturity of Jiyang depression[J]. Oil & Gas Geology, 1987, 8(2): 153-162. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT198702006.htm
[35] 彼得斯K E, 沃尔特斯C C, 莫尔多万J M. 生物标志化合物指南[M]. 张水昌, 李振西译. 北京: 石油工业出版社, 2011: 9-12. PETERS K E, WALTERS C C, MOLDOWAN J M. ZHANG Shuichang, LI Zhenxi. The biomarker guide[M]. ZHANG Shuichang, LI Zhenxi, translated. Beijing: Petroleum Industry Press, 2011: 9-12.
[36] 赵师庆, 王飞宇. 镜质组反射率的抑制效应及富氢镜质体的形成模式[J]. 淮南矿业学院学报, 1990, 10(3): 1-11. https://www.cnki.com.cn/Article/CJFDTOTAL-HLGB199003000.htm ZHAO Shiqing, WANG Feiyu. Suppression of vitrinite reflectance and origin model for perhydrous vitrinite[J]. Journal of Huainan Mining Institute, 1990, 10(3): 1-11. https://www.cnki.com.cn/Article/CJFDTOTAL-HLGB199003000.htm
[37] 童晓宁, 胡建芳, 祝孟博, 等. 分子标志物揭示的松辽盆地晚三冬期气候环境[J]. 地学前缘, 2017, 24(1): 154-165. https://www.cnki.com.cn/Article/CJFDTOTAL-DXQY201701011.htm TONG Xiaoning, HU Jianfang, ZHU Mengbo, et al. Late Santonian paleoenvironment reconstruction based on molecular markers in Songliao Basin, Northeast China[J]. Earth Science Frontiers, 2017, 24(1): 154-165. https://www.cnki.com.cn/Article/CJFDTOTAL-DXQY201701011.htm
[38] 刘大永. 中国典型含煤盆地镜质组结构特征及生烃、同位素动力学研究[D]. 广州: 中国科学院广州地球化学研究所, 2004. LIU Dayong. Vitrinites in typical coal-bearing basins of China: The molecular characterization and their kinetic studies on the hydrocarbon generation and carbon isotope fractionation[D]. Guangzhou: Guangzhou Institute of Geochemistry, Chinese, Chinese Academy of Sciences, 2004.
-
期刊类型引用(13)
1. 宁树正，张莉，徐小涛，张建强，邹卓. 新疆北部早、中侏罗世富油煤分布规律及控制因素. 煤炭科学技术. 2024(01): 244-254 . 
百度学术
2. 黄鹏程，郭伟勇，姬晓燕，蔡飞飞，张志峰，黄康，程云强，刘争，王贝，陈蓉，师庆民. 宁东煤田石炭-二叠系富油煤赋存的地质控制作用. 煤田地质与勘探. 2024(07): 119-131 . 本站查看
3. 师庆民，耿旭虎，王双明，蔡玥，韩波，王生全，张哲豪，何羽飞. 基于煤体真密度和自然伽马响应规律的富油煤判识. 煤田地质与勘探. 2024(07): 85-96 . 本站查看
4. 乔军伟，王昌建，赵泓超，师庆民，张煜，范琪，王朵，袁丹丹. 基于煤岩煤质多元指标的BP神经网络焦油产率预测方法研究. 煤田地质与勘探. 2024(07): 108-118 . 本站查看
5. 宋超，陈晓坤，徐勇，于志金. 含水率对油气伴生煤恒温热解后氧化特性的影响. 西安科技大学学报. 2024(04): 699-708 . 百度学术
6. 朱士飞，刘威，张静，秦云虎，毛礼鑫. 富油煤煤质特征与原位热解技术开发利用现状. 煤质技术. 2024(06): 23-33 . 百度学术
7. 鲍园，李争岩，安超，王双明，李丹. 多手段表征富油煤微生物厌氧发酵孔隙结构变化特征及机制. 煤炭学报. 2023(02): 891-899 . 百度学术
8. 杨甫，段中会，马丽，付德亮，田涛，贺丹，岳明娟. 陕西省富油煤分布及受控地质因素. 煤炭科学技术. 2023(03): 171-181 . 百度学术
9. 付德亮，段中会，杨甫，马丽，王振东，田涛，贺丹. 富油煤钻井式地下原位热解提取煤基油气资源的几个关键问题. 煤炭学报. 2023(04): 1759-1772 . 百度学术
10. 东振，张梦媛，陈艳鹏，冯烁，薛俊杰，陈浩，田继军，陈姗姗，赵宇峰，王兴刚，焦立新，李斌. 三塘湖-吐哈盆地富油煤赋存特征与资源潜力分析. 煤炭学报. 2023(10): 3789-3805 . 百度学术
11. 王贝，黄鹏程，郭伟勇，张志峰，姬晓燕，刘晶，蔡飞飞，虎晓金. 甜水河勘查区富油煤煤岩煤质及成煤环境. 新疆地质. 2023(04): 641-645 . 百度学术
12. 王双明，王虹，任世华，董书宁，郑德志，谭克龙，侯恩科，王生全，曲洋，焦小淼. 西部地区富油煤开发利用潜力分析和技术体系构想. 中国工程科学. 2022(03): 49-57 . 百度学术
13. 高文博，冯烁，田继军，吴斌. 三塘湖煤田汉水泉矿区富油煤赋存特征及沉积环境分析. 煤炭工程. 2022(10): 136-140 . 百度学术
其他类型引用(0)
计量
- 文章访问数: 279
- HTML全文浏览量: 18
- PDF下载量: 30
- 被引次数: 13
