兰坪盆地古近系云龙组元素地球化学特征及其古环境的恢复

Geochemical characteristics of elements in the Paleogene Yunlong Formation and the restoration of paleoenvironment in Lanping basin

  • 摘要: 为了恢复兰坪盆地古近系云龙组的沉积环境,采用电感耦合等离子体质谱(ICP-MS)方法对兰坪盆地古近系云龙组的石膏、灰岩、膏泥、泥岩和砂岩共计13件样品进行微量元素分析。根据各岩性中微量元素的蛛网图和m(Cu)/m(Zn)、m(Sr)/m(Cu)和m(Sr)/m(Ba)比值特征及Sr元素含量等恢复沉积环境及古气候。结果表明:石膏、灰岩、膏泥、泥岩和砂岩均有富集Rb、Pb、Zr的特征;石膏和膏泥形成于干热海相咸水的贫氧弱还原环境;砂岩和泥岩形成于温湿陆相淡水的富氧氧化环境;灰岩形成于干热海相咸水的富氧氧化环境。据此建立研究区沉积环境演化模式,并将其划分为2个阶段,第一阶段为气候干热的弱还原海相咸水湖沉积,沉积出石膏、灰岩和膏泥;第二阶段为温暖湿润的富氧氧化环境,沉积出砂岩、泥岩。这种沉积环境变化与古近纪云龙期气候环境周期性变化密切相关,同时也为盆地的矿产资源勘探提供依据。

     

    Abstract: In order to restore the sedimentary environment of the Paleogene Yunlong Formation in the Lanping basin, inductively coupled plasma mass spectrometry(ICP-MS) was used to analyze trace elements in 13 samples of gypsum, limestone, gypsum mud, mudstone and sandstone from the Paleogene Yunlong Formation in Lanping Basin. The sedimentary environments and paleoclimate are estimated based on the spider diagram of trace elements in each lithology and the characteristics of the ratio of Cu/Zn, Sr/Cu and Sr/Ba and the content of Sr. The results show that:gypsum, limestone, gypsum mud, mudstone and sandstone are all rich in Rb, Pb, Zr; gypsum and gypsum mud were formed in the dry and hot marine salt water in an lean oxygen and weak reduction environment; sandstone and mudstone were formed in oxygen-rich oxidation environment of warm and humid continental freshwater; limestone was formed in the oxygen-rich oxidation environment of dry and hot marine saline water. Based on this, the evolution model of sedimentary environment in the study area was established and divided into two stages. The first stage was the deposition of weakly-reduced marine saltwater lake with dry climate, and gypsum, limestone and gypsum mud were deposited. The second stage was a warm and humid oxygen-rich oxidation environment, where sandstone and mudstone were deposited. This change in sedimentary environment is closely related to the cyclical changes of the climate and environment in the Yunlong period, also provides a basis for the exploration of mineral resources in the basin.

     

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